Lithium samarium polyphosphate, LiSm(PO3)4
نویسندگان
چکیده
The mixed-metal rare-earth polyphosphate LiSm(PO(3))(4) consists of a three-dimensional framework in which zigzag [(PO(3))(n)](n-) chains with a periodicity of four PO(4) tetrahedra are connected through Li(+) and Sm(3+) ions (both with 2. symmetry).
منابع مشابه
Dilithium manganese(II) catena-tetrakis(polyphosphate), Li2Mn(PO3)4
The poly-phosphate Li2Mn(PO3)4 was synthesized and its structure characterized from powder diffraction data by Averbuch-Pouchot & Durif [J. Appl. Cryst. (1972), 5, 307-308]. These authors showed that the structure of this phosphate is isotypic to that of Li2Cd(PO3)4, as confirmed by the present work. The structure is built from infinite zigzag polyphosphate chains, [(PO3)(-)] n , extending alon...
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